
A brief discussion on the cleaning agent of lubricating oil additive
Release time:
2023-01-30
With the development of industrial technology, modern equipment requirements of high speed, high performance, high automation, high efficiency and long life, in terms of lubrication simply with mineral oil lubrication materials has been difficult to meet. Adding a small amount of other substances to a lubricating material can improve its performance, give it new characteristics, to meet the increasingly harsh use environment, these substances are called lubricating oil additives.
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Adding different additives to oil is the most economical and effective means to improve oil quality. Generally speaking, the variety and quality of lubricating oil often depend on the variety and quality of additives, so developing the production and use of additives has become an important way to make reasonable and effective use of resources, improve equipment performance and save energy.
Lubricating oil additives can be divided into cleaning agent, dispersant, antioxidant anti-corrosion agent, extreme pressure anti-wear
agent, oiliness agent and friction improver, antioxidant and metal deactivated agent, viscosity index improver, rust inhibitor, point reducing agent, anti-foam agent, etc. We will introduce the using of lubricating oil additives by several articles.
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- Introduction of cleansing agent
Cleaning agent is mainly used for internal combustion engine oil (engine oil, diesel oil, railway diesel engine oil, two stroke engine oil and Marine engine oil). Its main function is to keep the engine interior clean, so that the generated insoluble substances are colloidal suspension state, inhibit the further formation of carbon, paint film or sludge. Specifically, its functions can be divided into acid neutralization, solubilization, dispersion and washing.
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II. Function of Detergent
- Acid neutralization: The clean dispersant generally has a certain alkaline, some even high alkaline, it can neutralize the organic and inorganic acids generated by the oxidation of lubricating oil, prevent its further condensation, thus reducing the paint film, but also can prevent the corrosion of these acidic substances on the engine parts.
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2) Solubilization: Purifying dispersants are surfactants, which can dissolve solid or liquid substances that cannot be dissolved in oil in the micellar center composed of 5-20 surfactant molecules. In the process of use, it will dissolve oxygen compounds containing hydroxyl, carbonyl, carboxyl, nitro-compounds, water, etc. into micelles to form colloids. It can prevent further oxidation and condensation, reduce the formation and accumulation of harmful sediment on engine components.
3) Dispersion: can adsorb the generated carbon and paint film and other solid particles, so that it becomes a colloidal solution state dispersed in the oil, and it can prevent these substances to further condense into large particles and adhere to the machine parts, or deposition for sludge.
4)Clean: It can wash the paint film and carbon deposits that have been adsorbed on the surface of the parts and disperse them in the oil to keep the engine and metal surface clean.
The structure of the cleaning agent is basically composed of three groups: oleophilic, polar and hydrophilic. Because of the different structure, the performance of the cleaning agent is different.
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III. Classification of cleaning agent
The typical representative of the cleaning agent are sulfonate, alkyl phenol salt and salicylate. Depending on the chemical structure, there are mainly magnesium, calcium, barium formed compounds. According to the different chemical composition and base value, the detergent in different oil products meet the use of oil products through different components of the combination and dosage.
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- Sulfonate
Item | Metal content % | TBN /mgKOH/g | |
HY104 | Low base calcium petroleum sulfonate | ≥2.0 | 20--30 |
HY105 | Medium base calcium petroleum sulfonate | ≥6.85 | ≥145 |
HY106 | High base calcium petroleum sulfonate | ≥11.6 | ≥290 |
HY106D | Super basic calcium petroleum sulfonate | ≥15.0 | ≥390 |
HY107 | Super basic magnesium petroleum sulfonate | ≥8.5 | ≥390 |
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2) Alkyl phenol salts
Item | Metal content % | TBN /mgKOH/g | |
HY115B | Calcium alkyl phenols sulfide with high base value | ≥8.9 | ≥240 |
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- Salicylate
Item | Metal content % | TBN /mgKOH/g | |
HY109 | Medium base value calcium alkyl salicylate | 5.5—6.0 | ≥150 |
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A brief discussion on the cleaning agent of lubricating oil additive
With the development of industrial technology, modern equipment requirements of high speed, high performance, high automation, high efficiency and long life, in terms of lubrication simply with mineral oil lubrication materials has been difficult to meet. Adding a small amount of other substances to a lubricating material can improve its performance, give it new characteristics, to meet the increasingly harsh use environment, these substances are called lubricating oil additives.
Main function and classification of dispersant lubricant additive (2)
The oil soluble group provided by the dispersant is larger than the purifier, which can effectively prevent the accumulation of carbon and colloidal material together.
Main function and classification of dispersant lubricant additive (1)
In the early stage, the widely used detergent dispersants in internal combustion engine oil are metallic sulfonates, alkyl phenols, phosphonates and alkyl salicylate, which are called metal detergent dispersants. Subsequently developed a metal-free additive, it has excellent dispersion properties, in order to distinguish from the former, people called it ash-free powder.
The effect of viscosity index improver on the fuel economy of gasoline engine oil. The high frequency reciprocating tester was used to simulate the friction of the engine, and the lubrication performance of gasoline engine oil was investigated by measuring the friction factor. The smaller the friction factor of gasoline engine oil, the better the lubricating performance and the more conducive to improving fuel economy. The friction torque of gasoline engine oil was measured by engine drag test and compared with the friction torque of reference oil. The greater the torque difference (torque difference = the average value of the friction torque of the reference oil - the friction torque of the gasoline engine oil), the better the fuel economy of the gasoline engine oil. The friction coefficient of gasoline engine oil of 0W-20 viscosity grade prepared with polymethacrylate with smaller kinematic viscosity (kinematic viscosity at 100 ℃ of 890 mm2/s) and better shear stability (shear stability index 5) is higher than that of gasoline engine oil. Small, large torque difference, with better fuel economy. According to NEDC (New European Driving Cycle) simulation cycle test fuel consumption calculation, it can improve fuel economy by 0.28%. According to the "Passenger Vehicle Fuel Consumption Limits" issued by the Ministry of Industry and Information Technology: GB16578-2014 and "Passenger Vehicle Fuel Consumption Evaluation Methods and Indicators": GB27999-2014 mandatory standards, by 2020, all passenger vehicles will be The average fuel consumption of 100km must be reduced to 5.0L, so saving fuel and reducing fuel consumption is the general trend of the current automobile industry development. In order to reduce fuel consumption and improve fuel economy, in addition to improving the design of the engine, it is also an effective way to improve the lubrication state between the friction parts of the engine. Generally speaking, during the operation of the engine, the bearing parts are mainly in the state of elastic fluid lubrication, while the parts such as the valve train, piston and cylinder liner are mainly in the state of boundary lubrication and mixed lubrication. For fluid lubrication state, choosing low-viscosity gasoline engine oil can reduce friction loss; for boundary lubrication state, adding friction modifier to engine oil is a more effective method to reduce friction loss. For the mixed lubrication state, it is necessary to comprehensively consider the optimization of the viscosity characteristics and friction characteristics of gasoline engine oil. In order to improve the fuel economy of passenger cars, it is necessary to study the effect of gasoline engine oil components on fuel economy. As an additive that can improve the viscosity-temperature properties of lubricating oils, viscosity index improvers have been widely used in engine oils. Commonly used viscosity index improvers are hydrogenated styrene diene copolymer (HSD for short), olefin copolymer (OCP for short), polymethacrylate (PMA for short), hydrogenated styrene-isoprene copolymer (SDC) And polyisobutylene (PIB) etc. The overall performance of OCP and HSD is better, but HSD has better shear resistance than OCP, and is more commonly used in high-grade gasoline engine oil. PMA has the characteristics of improving the low temperature performance of gasoline engine oil and increasing the viscosity index, and is also widely used in high performance gasoline engine oil. Some studies have reported that gasoline oil formulated with PMA viscosity index improver helps to form a boundary oil film on the metal surface under high temperature and low speed conditions, thereby significantly reducing friction and improving the fuel economy of gasoline oil.
The chemical properties of propylene are determined by its double bond and the hydrogen atom on the allyl group. In the molecular structure of propylene, only the projection on the main plane shows a low degree of symmetry, making it the smallest stable-state unsaturated hydrocarbon. This asymmetry is also manifested in the dipole moment of propylene is only 0.35D, which is prone to various types of chemical reactions. The carbon atoms at position 1 and 2 are the same as the molecular structure of ethylene. On the same triangular plane, they cannot rotate freely due to the existence of double bonds. The carbon atom at position 3 is in a tetrahedron like methane and can rotate freely. The hydrogen atom on it is attracted by the carbon atom. The hydrogen atom on the allyl group is the main reason that makes its chemical properties different from ethylene. Propylene molecules can undergo self-addition reactions. When phosphoric acid, boron fluoride or sulfuric acid are used as catalysts on solids, the reaction proceeds according to the carbanion mechanism. At low temperatures, the main product of propylene dimerization is 4-methyl- 2-pentene. For example, alkyl alkali metal and certain alkali metal compounds are used as catalysts to dimerize propylene. The reaction proceeds in the direction of carbanion, and the product is mainly 4-methyl-1-pentene. Due to the asymmetry of the propylene molecule, the displacement of the double bond and the conversion of the cis-trans structure at the same time, the product composition may include various hexene isomers and olefins above C6. C6 olefins can be used as raw materials for synthetic polymers, gasoline blending agents, etc. [4]. Propylene is oligomerized on an acid catalyst to produce nonene and dodecene. When propylene is co-oligomerized with a mixture of butene, the polymer contains a large amount of heptene. Using aluminum alkyl and titanium trichloride as catalysts or metallocene and methylaluminoxane as catalysts, propylene polymerization is carried out in bulk, emulsion or gas phase at a certain temperature and pressure to obtain polypropylene.
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Mainly include: alcohol-resistant foam, dry powder, carbon dioxide, sand and so on. Fire fighting method: Move the container from the fire scene to an open place as much as possible. Spray water to keep the fire container cool until the end of the fire extinguishing. If the container in the fire scene has changed color or produces sound from the safety relief device, it must be evacuated immediately.